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BIO
DIESEL |
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The new world trend requires the utilization
of bio-fuels, in order to limit the gas emissions, with nearly closed
CO2 loop in case of Biodiesel. In the future the trend will be the
shifting from petroleum based fuel to bio-fuels. Biodiesel can be
used alone or blended with diesel oil, either for heat production
or as automotive fuel.
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SOME BIODIESEL ADVANTAGES |
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- Well bio-degradable
- Reduced gas emissions
- Sulphur-free
- Less toxic
- Less smoke from combustion
- Without aromatics
- Safe to handle.
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THE PROCESS |
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Biodiesel is a methylester of fatty acids obtained from fatty matters
(FAME)
Oils and fats, of vegetable or animal origin, can be transformed by
the chemical reaction of transesterification into a bio-fuel. In this
process the triglycerides react with methanol forming methylesters
and glycerine in presence of an alkaline catalyst. The product is
a mixture of methylesters with different chain length. The reaction
is carried out in two stages stirred reactors, followed by a settling
section: here the methylesters is separated as light phase from glycerine
and water as heavy phase. Then both methylesters and glycerin are
desolventized in order to remove the alcohol which is recovered and
recycled, while the methylesters is washed and dried to obtain Biodiesel
ready for utilization. |
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BIODIESEL PRODUCTION |
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Feedstock:
Many oils and fats can be transesterified. In order to obtain specific
fuel properties, in Europe pre-treated oils from rapeseed and sunflower
seed are preferred. Other oils, soya, palm etc can be processed too.
An oil pre-treatment is required to meet the feed specification and
it is variable depending on the starting feedstock quality. The feed
oil must meet the following specifications :
FFA Content : 0.1 % max.
Moisture : 0.1 % max.
Phosphorus : 10 ÷ 15 ppm
Cold test (AOCS) : 5.5 h at 0ºC
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